First George Clooney is on Film 2006 this week. He is mostly talking about Good Night and Good Luck, but he might mention Syriana, (or they could leave that until it's released here).
The second show is The Culture Show. Here is the press release for the 2nd March show.
The latest big-name interview
Actor and director George Clooney talks about his vision for cinema
The Culture Show
Thursday 2 March on BBC TWO
The show is usually shown twice. Once at 7pm and then again later at 11.20pm. So if you miss the first you might be able to catch the 2nd.